In a small bowl, add 4 oz water and vanilla extract. Sprinkle gelatin on top.
Add the remaining ½ cup (4 ounces) water, corn syrup, sugar, and salt in a 3-quart stainless steel pot and set over medium heat.
Stir mixture with a fork until bubbling, about 5 minutes, then increase heat to medium-high. Clip on a digital thermometer and cook, without stirring, until the clear syrup registers 250°F, about 5 minutes.Transfer the thermometer to the bowl of a stand mixer and pour in the hot syrup all at once, scraping the pot with a heat-resistant spatula. Cool to exactly 212°F, about 6 minutes. Add gelatin. With the whisk attachment, mix on low speed, then increase to medium-high and whip until thick, snowy white, roughly tripled in volume, and beginning to ball up around the whisk, about 10 minutes. Reduce the speed to low, add melted butter, return to medium-high, and beat for a few seconds more.
Scrape the creamy marshmallows on top of the graham layer, spreading it into an even layer. Cover with foil and refrigerate until firm, about 2 hours (or let stand overnight at room temperature).
To cut the bars, use a large chef's knife, and coat the knife blade with a bit of powdered sugar before and in between cuts. You can also run the blade under hot water, then wipe it dry to make clean cuts.